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II. Kémiai Házi dolgozat

2008.03.26

1, Részletezze az ammónia gyártás folyamatát (hőmérséklet, katalizátor, nyomás)

 

Az ammónia közönséges körülmények között színtelen, szúró szagú, a levegőnél kisebb sűrűségű gáz. Forráspontja alacsonyabb, mint a vízé, de ez az érték a hasonló moláris tömegű metánhoz, illetve a nála nagyobb moláris tömegű kén-hidrogénhez (H2S) vagy hidrogén-kloridhoz képest is jóval nagyobb. Ennek a molekulák között létrejövő hidrogénkötés az oka. Az ammóniagáz összenyomással könnyen cseppfolyósítható, amit ugyancsak a hidrogénkötések kialakulásával hozhatunk összefüggésbe. A cseppfolyósított ammónia párolgásakor nagy mennyiségű hőt képes környezetéből elvonni. Ezt a tulajdonságát használják ki, amikor az ún. kompressziós hűtőszekrények hűtőfolyadékaként használják. Az ammónia kitűnően oldódik vízben. A vízoldékonyságnak a víz és az ammóniamolekulák között kialakuló hidrogénkötéseken kívül az a magyarázata, hogy a vegyület kémiai reakcióba lép a vízzel. Az ammónia bázis, ezért vizes oldata lúgos kémhatása miatt ruhák tisztítására (zsírfoltok eltávolítására) használják. A szalmiákszeszt tévesen ammónium- hidroxidnak is nevezik. Az ammónia 1 mol/dm3 koncentrációjú oldatában a molekuláknak csupán 0,5%-a lép kémiai reakcióba a vízzel, vagyis az oldat viszonylag kevés hidroxidiont tartalmaz. Az ammónia tehát gyenge bázis. Az ammóniaoldat bepárlásával sem lehet ammónium-hidroxid kristályokat elkülöníteni, mert az ammónia elillan az oldat melegítése közben. A szalmiákszeszből elillanó amminógáz reakcióba lép a hidrogén-klorid-gázzal A folyamat során fehér füst, azaz szilárd anyag keletkezik. Az átalakulás során a hidrogén-klorid-molekulák nem a vízben disszociálnak, hanem közvetlenül az ammóniamolekulának adják át protonjaikat (hidrogénionjaikat). Ellentétes töltésű ionok keletkeznek, amelyek ellentétes töltésű ionok erős vonzásuk révén szilárd kristályba rendeződnek: ezért látjuk a füst megjelenését. Az ammónia más savakkal is a fentihez hasonló reakcióba lép, s a folyamat során képződő ammóniavegyületek (NH4NO3, (NH4)2CO3, (NH4)2SO4 stb.) mind magas olvadáspontú, szilárd halmazállapotú, vízben kitűnően oldódó ionvegyületek. Az ammóniát az iparban elemeiből szintetizálják Az ammónia felhasználása széles körű. A korábban említetteken kívül sokféle vegyület (salétromsav, műtrágya, robbanószert stb.) ipari előállításra használják. Hazánk legfontosabb ammóniagyártó üzeme korábban a Péti Nitrogénművek volt, a műtrágyaként ismert pétisó neve is innen származik.

 

2, A fehér foszfor és a vörös foszfor összehasonlítása.

 

Módosulatai 

      Fehér   

       Vörös 

Szerkezete

 P4, molekularácsos

  P  atomrács

Fizikai tulajdonságok 

Sárga, szilárd anyag

Vörös, szilárd anyag

                   Vízben oldhatatlan

Zsíroldószerek jól oldják

Zsíroldószerekben is olhatatlan

Kémiai sajátossá

                          Éghető

Alacsonyabb gyulladási hőmérséklet

Magasabb gyulladási hőmérséklet

Elfordulása

Vegyületekben (foszfátok, csont, DNS)

 

 

                   

 

 

 

 

 

 

 

 

 

 

 

3, Mit nevezünk?

 

a, választóvíznek: A salétromsav oldja az ezüstöt, de az aranyat nem, a két fém szétválasztására használják az ékszerek, ezért a salétromsavat választóvíznek is, nevezik.

 

b, kristályvíznek: salétromsav: sósav 1:3 arányú elegye a kristályvíz            oldja: Aranyat, platina

 

c, fém felület passzivitása:

 

d, nitrózus gáz: A nitrózus gázok nitrogén-monoxidot (NO) és nitrogén-dioxidot (NO2) tartalmazó gázok.

4, Egészítse, ki a táblázatott

 

 

Név

Fontőssága (felhasználás, előfordulás)

NH4NO3

Pétisó

Műtrágya, Mezőgazdaságban  

H3PO4

Foszforsav

Az ember RNS és DNS alkotóeleme, csontszövetben is előfordul

HN3

Ammónia

Salétromsav, műtrágya, robbanószer

Ca3(PO4)2

Vörös foszfor

Foszforsav és foszfátok Felhasználás: Gyufánál, Petárdáknál

P

Foszfor

Foszforsav és foszfátok Gyufánál, Petárdáknál

 

 

Hozzászólások

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(Roberthew, 2020.02.09 00:26)

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(Roberthew, 2020.02.08 23:38)

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(Roberthew, 2020.02.08 22:51)

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joined:May 25, 2019posts:195:22 pm on Oct 3, 2019 (gmt 0)


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